Odpowiedź:
Wyjaśnienie:
V = 200cm³=0,2dm³
m kwasu=0,04g
m soli = 0,04g
Ka = 1,76*10⁻⁵
pKa = 4,76
M CH₃COOH = 60g/mol
1 mol.............60g
x moli.............0,04g
x = 0,00067 mola
Cm = n/V
Cm = 0,00067/0,2
Cmk = 0,00335mol/dm³
M CH₃COONa = 82g/mol
1 mol.............82g
x moli.............0,04g
x = 0,00049 mola
Cm = n/V
Cm = 0,00049/0,2
Cms = 0,00245mol/dm³
Pomijam autodysocjację wody:
[CH₃COOH] = ck = 0,00335mol/dm³
[CH₃COO⁻] = cs = 0,00245mol/dm³
pH = pKa -log(Ck/Cs)
pH = 4,76 - log(0,00335/0,00245)
PH = 4,76 -log(1,3673)
pH = 4,76 + 0,136
pH = 4,896
[H⁺] = 10^-pH
[H⁺] = 10⁻⁴'⁸⁹⁶
[H+] = 0,00001271 = 1,271*10⁻⁵mol/dm³