Odpowiedź:
Zad 10.
AB<=>A^(+)+B^(-)
n(0)=1,5mol
alfa=0,5%=0,005
V=const=1 => n(0)=Co gdyz Co=n(0)/V.
[A^(+)]=[B^(-)]=x
x=Co*alfa=1,5*0,005=7,5*10^(-3)mol
[AB]nz=Co-x=1,5-0,0075=1,4925mol
Zadanie 43.
ms1+ms2=msx gdzie
ms2=(Cp2*mr2)/100%
ms1=x
msx=(Cpx*mrx)/100%
mrx=mr1+ms1=200g
Cpx=5%
Cp2=0,5%
mr2=200-ms1=(200-x)g
ms1+(Cp2*mr2)/100%=Cpx*[(ms1+mr2)/100%]
x+(0,5*(200-x))/100=5*(x+(200-x))/100
x+(100-0,5x)100=(5*(x+200-x)/100)
x+1-0,005x=10
0,995x=9
x=9,045g
Zadanie 44.
Cm1=4mol/dm3
V1=x
mr2=50g => V2=50cm3(dH2O=1g/cm3)
Cm2=0mol/dm3
Cmx=1,5mol/dm3
Vx=(50+x)cm3
n1+n2+nx gdzie n1=Cm1*V1, n2=Cm2*V2, nx=Cmx*Vx
zatem
Cm1*V1+Cm2*V2=Cmx*Vx
4*x+0*50=1,5*(50+x)
4x=75+1,5x
2,5x=75
x=30cm3